Synthesis and Conformational Analysis of Six-Membered Cyclic Phenyl Phosphites
A procedure for synthesizing potentially anancomeric equatorial phenyl phosphites (cis-1 and eq-cis-2) is reported.Spectral characteristics and low-temperature NMR studies on the phenyl phosphites suggest that eq-cis-2 is a system with a predominant chair conformation in solution.On the contrary, cis-1 is conformationally heterogeneous.
Gordillo, Barbara,Garduno, Catalina,Guadarrama, Gerardo,Hernandez, Javier
p. 5180 - 5185
(2007/10/02)
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