- Synthesis and Conformational Analysis of cis,cis-1,3,5-Trimethylcyclohexane-1,3,5-tricarboxylic Acid
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Conversion of 3,5,7-trimethyladamantan-1-ol to a hypobromite, fragmentation in situ, and oxidation with KMnO4 generate the lactone, 6, of cis,cis-1,3,5-trimethyl-1-(hydroxymethyl)cyclohexane-3,5-dicarboxylic acid, which can in turn be oxidized by RuO4-HIO
- Kemp, D. S.,Petrakis, Konstantinos S.
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- 3,5,7-Trimethyl-1-azatricyclo[3.3.1.13,7]decan-2-ylidene, an Aminocarbene without π conjugation
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3,5,7-Trimethyl-1-azatricyclo[3.3.1.13,7]decan-2-ylidene, an aminocarbene without π conjugation, has been generated from the corresponding tosylhydrazone salt. Addition of the carbene to alkenes is stereospecifically cis, thus showing that the
- Ye, Qing,Komarov, Igor V.,Kirby, Anthony J.,Jones Jr., Maitland
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p. 9288 - 9294
(2007/10/03)
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