- Polybromoaromatic compounds: X. Reactions of polybromobenzenes with primary and secondary amines
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Polybromobenzenes C6Br5X (X = Br, F, CN, NO 2) react with primary amines (methylamine and cyclohexylamine) to give nucleophilic substitution products; reactions of the same substrates with secondary amines (dimethylamine, diethylamine, piperidine, and morpholine) are accompanied by hydrodebromination processes.
- Shishkin,Esina,Lapin,Butin
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- Regioselectivity of methoxydebromination of substituted pentabromobenzenes C6Br5X in pyridine
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The kinetics and regioselectivity of methoxydebromination of some substituted pentabromobenzenes C6Br5X (X = NO2, CN, NH2, MeNH, and MeO) were studied in pyridine at 115 deg C.The partial rate factors (kf) were calculated for different position
- Shishkin, V. N.,Lapin, K. K.,Shabarina, S. A.,Butin, K. P.
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p. 1715 - 1719
(2007/10/03)
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