The First Phase-transfer catalysed Reactions of Trialkylboranes. A Highly Facile Synthesis of Trialkylmethanols from Alkenes
The phase-transfer catalysed reactions of trialkylboranes, generated in situ via hydroboration of alkenes, with chloroform and aqueous sodium hydroxide, followed by treatment with hydrogen peroxide, provide an economic and convenient metod for the synthesis of trialkylmethanols.
Junchai, Bai,Hongxun, Ding
p. 323
(2007/10/02)
LITHIUM TRIS(PHENYLTHIO)METHANE FOR THE HOMOLOGATION OF TRIALKYLBORANES: CONVENIENT SYNTHESES OF KETONES AND t-CARBINOLS
Lithium tris(phenylthio)methane is a readily available, cheap reagent for the production of ketones and t-carbinols from trialkylboranes.The scope and limitations of the reactions are indicated as are some of its unique features.
Pelter, Andrew,Rao, J. Madhusudhana
p. 65 - 70
(2007/10/02)
Synthesis of Ketones and Tertiary Alcohols from Trialkylboranes. Use of Lithium Tris(phenylthio)methanide
The interaction of lithium tris(phenylthio)methanide with trialkylboranes followed by oxidation allows the production of ketones or tertiary alcohols in good yields under mild conditions.
Pelter, Andrew,Rao, J. Madhusudhana
p. 1149 - 1150
(2007/10/02)
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