The ligand-exchange process of P-Hapical phosphoranes and the thermal formation and pseudorotation of anti-apicophilic spirophosphoranes
Monocyclic P-Hapical phosphoranes 10 bearing a ring-opened Martin ligand are formed upon treatment of the P-Hequatorial spirophosphorane 7 with more than 2 equiv. of alkyllithium compounds. A ligand-exchange process of these phos-pho
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