- Reactions of Spirohept-4-ene Derivatives with Tetracyanoethylene. Extensive Rearrangements Involving the Aza-Cope Process
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In CH2Cl2 or CH3CN, 1,1-dicyclopropylspirohept-4-ene (4a) reacted readily with TCNE in a unique manner to give 4--6-methylenebicyclooct-3-ene-2,2,3-tricarbonitrile (8a), an imine after extensive rearrangements,
- Nishida, Shinya,Asanuma, Naoki,Murakami, Masashi,Tsuji, Takashi,Imai, Toshiro
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p. 4658 - 4663
(2007/10/02)
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- DEBROMINATION OF 1,1-BIS(BROMOMETHYL)CYCLANES
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It was shown that the composition of the debromination products from 1,1-bis(bromomethyl)cyclanes depends on the strain energy of the initial ring.
- Slobodin, Ya.M.
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p. 459 - 461
(2007/10/02)
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