Photo-induced Reactions of Some Epoxides in Isopropanol: Effect of Structural Parameters on Photoreduction and Photosolvolysis
Competing photoreduction and photosolvolysis reactions have been observed in the photolysis of a number of epoxides (1-8).Certain epoxides display extreme photobehaviour; photosolvolysis is the exclusive process in 5 and 7 whereas 8 undergoes only photoreduction.A novel photo-Wagner-Meerwein rearrangement occurs in the photosolvolysis of benzonorbornene epoxide (7).Mechanisms involving radical and ionic intermediates are discussed.
Sonawane, H. R.,Sethi, S. C.,Merchant, S. N.
p. 934 - 939
(2007/10/02)
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