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20096-53-1

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Spectroscopic determination of pressure-induced shifts in inclusion complexation equilibria
The effect of modest hydrostatic pressure (c ranging from clearly pressure dependent (-14%) to pressure independent over 338 bar. Additional solvation perturbations are observed in the pressure dependence of the quantum efficiency for both complexes (-7.3% and -9.4%). Thus, pressure-induced perturbation in the fluorescence properties of the complex need not be accompanied by simultaneous changes in the complexation equilibrium. Finally, these pressure-induced changes in complexation selectivity are important for all measurements conducted under variable pressure conditions, including liquid chromatography and process monitoring.
Evans, Christine E.
p. 2136 - 2142
(2007/10/03)

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Chemical Properties

Density: 1.409 g/cm³
Refractive Index: 1.71
PKA: 0.50±0.40(Predicted)
PSA: 74.78000
LogP: 4.98390

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