- Synthesis method of halogenated aniline
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The invention provides a synthesis method of halogenated aniline. The synthesis method comprises the following steps: taking a carbon-coated nickel nano composite material containing alkaline-earth metals as a catalyst, and catalyzing a hydrogenation reduction reaction of halogenated nitrobenzene in a hydrogen atmosphere, wherein the nano composite material contains a core-shell structure with a shell layer and an inner core, the shell layer is a graphitized carbon layer containing alkaline-earth metals and oxygen, and the inner core is nickel nano particles. According to the method, the nanocomposite material is used as a catalyst; a carbon material and the nickel nano particles generate a synergistic effect and a good catalytic effect, the alkaline-earth metals of the shell layer further synergistically improve the catalytic performance of the nano composite material, and the catalyst is used for hydrogenation reduction of halogenated nitrobenzene to synthesize halogenated aniline,has excellent activity, selectivity and safety, and can effectively solve the dehalogenation problem in the reaction process.
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Paragraph 0156-0158
(2020/08/09)
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- Synthesis method of halogenated aniline
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The invention provides a synthesis method of halogenated aniline. The synthesis method comprises the following steps: taking a carbon-coated nickel nano composite material containing alkali metals asa catalyst, and catalyzing a hydrogenation reduction reaction of halogenated nitrobenzene in a hydrogen atmosphere; wherein the nano composite material contains a core-shell structure with a shell layer and an inner core, the shell layer is a graphitized carbon layer containing alkali metals, nitrogen and oxygen, and the inner core is nickel nano particles. According to the method, the nano composite material is used as a catalyst; a carbon material and the nickel nano particles generate a synergistic effect and a good catalytic effect, the alkali metals of the shell layer further synergistically improve the catalytic performance of the nano composite material, and the catalyst is used for hydrogenation reduction of halogenated nitrobenzene to synthesize halogenated aniline, has excellentactivity, selectivity and safety, and can effectively solve the dehalogenation problem in the reaction process.
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Paragraph 0141-0143
(2020/08/09)
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- Synthesis method of halogenated aniline
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The invention provides a synthesis method of halogenated aniline. The synthesis method comprises the following steps: taking a carbon-coated nickel nano composite material containing alkaline-earth metals as a catalyst, and catalyzing a hydrogenation reduction reaction of halogenated nitrobenzene in a hydrogen atmosphere; wherein the nano composite material contains a core-shell structure with a shell layer and an inner core, the shell layer is a graphitized carbon layer containing alkaline-earth metals, nitrogen and oxygen, and the inner core is nickel nano particles. According to the method,the nano composite material is used as a catalyst; a carbon material and the nickel nano particles generate a synergistic effect and a good catalytic effect, the alkaline-earth metals of the shell layer further synergistically improve the catalytic performance of the nano composite material, and the catalyst is used for hydrogenation reduction of halogenated nitrobenzene to synthesize halogenatedaniline, has excellent activity, selectivity and safety, and can effectively solve the dehalogenation problem in the reaction process.
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Paragraph 0103; 0140-0142
(2020/08/09)
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- Halide ion trapping of nitrenium ions formed in the Bamberger rearrangement of N-arylhydroxylamines. Lifetime of the parent phenylnitrenium ion in water
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The data of p-aminophenol, the product of Bamberger rearrangement, Were analyzed by a mechanism involving rate-limiting formation of the appropriate arylnitrenium ion followed by product-determining steps in involving trapping by the solvent or by the added halide. The possibility that a portion of the halide-trapped products were derived from a pre-association mechanism was also include. Kinetic analyses then produced kBr:kw and kCl:kw ratios for two limiting cases, one involving pre-association with an equilibrium constant Kas = 0.3, and one ignoring pre-association. From an azide:water ratio (kAz:kw) previously determined for the 2,6-dimethylphenylnitrenium, kBr was concluded to lie in the range (4-5) × 109 M-1 s-1 for all of the nitrenium ions of this study. This range for kBr then led to kw values of (1-2) × 109 s-1 (2,5-Me2), (2-3) × 109 s-1 (2-Me), and (4-8) × 109 s-1 (parent and 2-Cl), where the ranges reflect uncertainties in the exact value of kBr and in the contribution from pre-association. The lifetime of the parent phenylnitrenium ion in water at one molar ionic strength is concluded to lie in the range 125-250 ps.
- Fishbein,McClelland
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p. 1321 - 1328
(2007/10/03)
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