- REACTIONS OF PERFLUORONITRILES. II. INTERACTIONS WITH PHENYLPHOSPHINE
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Treatment of perfluoro-n-octanonitrile with phenylphosphine gave tetraphenyltetraphosphine and a spectrum of reduction and interaction products.Fifteen compounds were identified.The imine, (Rf=C7F15) RfCH=NH, and the amine, RfCH2NH2, were the primary reduction products.Secondary phosphorus-free products, some formed following ammonia evolution, were the following: RfCH=NCH2Rf, RfCH2CH(NH2)Rf, RfC(=NH)N=CRf(NH2), RfCH2NHCRf(=NH), (RfCN)3, RfCH=NCRf=NCRf(=NH), RfCH2N=CRfNHCH2Rf, and RfCH2N=CRfNHCRf(=NH).Only three phosphorus-containing materials were definitely identified: RfCH(NH2)P(C6H5)H, RfCHN=CHRf, and RfC(=NH)P(C6H5)CRf(=NH).Depending on reaction conditions, specific phosphorus-containing compounds could be preferentially produced.All the structure assignments are based solely on mass spectral breakdown patterns, since pure compounds were not isolated.
- Paciorek, K. J. L.,Nakahara, J. H.,Kratzer, R. H.
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- REACTIONS OF PERFLUORONITRILES. I. INTERACTIONS WITH ANILINE
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Perfluoro-n-octanonitrile was found to react with aniline both in the absence and presence of solvents.A spectrum of products was formed including tris(perfluoro-n-heptyl)-s-triazine, N-phenyl-perfluoro-n-octylamidine, and N'-(perfluoro-n-octylimidoyl)-N-phenyl-perfluoro-n-octylamidine, as well as the diphenyl analogues of the last two compounds.The reaction mechanisms, infrared and mass spectra are discussed.
- Paciorek, K. J. L.,Nakahara, J. H.,Kratzer, R. H.
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