- Synthesis of C-glycosyl lactones and protected C-glycosyl amino acids: Use of radical cyclization
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Protected carbohydrates 6a-13a, having one free hydroxyl and a phenylseleno group or halogen on the adjacent carbon, were condensed with (2,2-diphenylhydrazono)acetic acid (2); the resulting esters undergo radical cyclization to afford carbohydrates fused to a 2,2-diphenylhydrazino lactone unit (6c,d-13c,d). In suitable cases (9c,d) such carbohydrate lactones can be elaborated into C-glycosyl amino acids.
- Zhang, Junhu,Clive, Derrick L. J.
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p. 770 - 779
(2007/10/03)
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