On Anchimerically Assisted Homolysis via Sulphide Functions
In contrast to O-O fission, anchimeric assistance from sulphide functions in the rate of unimolecular fission of the N-O bond is only marked for heterolysis reactions; analogous homolyses are very much less accelerated, although bridged radical intermediates are involved.
Lawson, Alexander J.
p. 1238 - 1239
(2007/10/02)
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