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236743-98-9

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Synthesis of ecteinascidin ET-743 and phthalascidin Pt-650 from cyanosafracin B
(equation presented) An efficient new process is described for the synthesis of ecteinascidin ET-743 (1) and phthalascidin (2), starting from readily available cyanosafracin B (3).
Cuevas, Carmen,Perez, Marta,Martin, Maria J.,Chicharro, Jose L.,Fernandez-Rivas, Carolina,Flores, Maria,Francesch, Andres,Gallego, Pilar,Zarzuelo, Maria,De La Calle, Fernando,Garcia, Jesus,Polanco, Concepcion,Rodriguez, Ignacio,Manzanares, Ignacio
p. 2545 - 2548
(2007/10/03)

Enantioselective synthesis of saframycin A and evaluation of antitumor activity relative to ecteinascidin/saframycin hybrids.
[formula: see text] A short synthesis of saframycin A is described which begins with a readily available intermediate previously utilized for the total synthesis of ecteinascidin 743. A key step in this synthesis is the use of 1-fluoro-3,5-dichloropyridin
Martinez,Corey
p. 75 - 77
(2008/02/11)

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Chemical Properties

Boiling Point: 705.5±60.0 °C(Predicted)
Density: 1.35±0.1 g/cm3(Predicted)
PKA: 14.28±0.10(Predicted)

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