cas 24108-40-5, 3-Phenyl-1,2,4-triazine | Articles data ｜lookchem

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24108-40-5

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Reinvestigation of the reaction of 3-substituted 1,2,4-triazines with nitronate anions: unexpected behavior of 3-(2-ethoxyphenyl)-1,2,4-triazine in the reaction with anions of nitroalkanes
[Figure not available: see fulltext.] 3-Substituted 1,2,4-triazines easily react with nitronate anions to replace hydrogen atom in the position C-5 according to nucleophilic substitution mechanism and form appropriate oximes of 5-formyl- or 5-acyl-1,2,4-t
Mojzych, Mariusz,Bernat, Zofia,Karczmarzyk, Zbigniew
p. 968 - 977
(2019/11/14)

1,2,4-Triazines Are Versatile Bioorthogonal Reagents
A new class of bioorthogonal reagents, 1,2,4-triazines, is described. These scaffolds are stable in biological media and capable of robust reactivity with trans-cyclooctene (TCO). The enhanced stability of the triazine scaffold enabled its direct use in recombinant protein production. The triazine-TCO reaction can also be used in tandem with other bioorthogonal cycloaddition reactions. These features fill current voids in the bioorthogonal toolkit.
Kamber, David N.,Liang, Yong,Blizzard, Robert J.,Liu, Fang,Mehl, Ryan A.,Houk,Prescher, Jennifer A.
supporting information
p. 8388 - 8391
(2015/07/15)

A general approach to selective functionalization of 1,2,4-triazines using organometallics in palladium-catalyzed cross-coupling and addition reactions
A selective way to obtain disubstituted 1,2,4-triazines in good yields by combining addition reactions and palladium-catalyzed cross-coupling reactions of organometallics with 3-methylsulfanyl-1,2,4-triazine is described.
Alphonse, France-Aimee,Suzenet, Franck,Keromnes, Anne,Lebret, Bruno,Guillaumet, Gerald
p. 2893 - 2899
(2007/10/03)

Copper(I)-promoted palladium-catalyzed cross-coupling of unsaturated tri-n-butylstannane with heteroaromatic thioether
(Matrix presented) Palladium-catalyzed cross-coupling of vinyl- and arylstannanes with π-electron-deficient heteroaromatics was performed in good yields. This Stille-type reaction was carried out with a methylthioether function as an electrophile in the presence of a copper(I) bromide-dimethyl sulfide complex.
Alphonse, France-Aimee,Suzenet, Franck,Keromnes, Anne,Lebret, Bruno,Guillaumet, Gerald
p. 803 - 805
(2007/10/03)

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Chemical Properties

Melting Point: 52-53 °C(Solv: hexane (110-54-3); ethyl ether (60-29-7))
Boiling Point: 329.5 °C at 760 mmHg
Flash Point:156.1 °C
Density: 1.169 g/cm³
PKA: 0.94±0.63(Predicted)
PSA: 38.67000
LogP: 1.53860

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