- Extremely Reactive C=C Double Bonds, VI. - Tris(methylphenylamino)methane - The Chemistry of Orthoamides
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Reactions of the title compound 2 with sulfur, selenium, thiophenol, malononitrile, 1,3-indanedione, fluorenone hydrazone, phenylmagnesium bromide, bromine, thioacetic acid, N,N'-diphenylurea, oxalyl chloride, 9,9-dichloroxanthene, phenyl isocyanate, and stilbene dibromide are described and the mechanisms are discussed.The catalytic influence of 2 on the decomposition of 9-diazofluorene in xylene and mesitylene is discussed.
- Schoenberg, Alexander,Singer, Erich,Stephan, Werner
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p. 1581 - 1588
(2007/10/02)
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- β,β-Diacyl-enamine und -enole, 9. Zur Darstellung von Aminomethylenderivaten offenkettiger CH2-acider Verbindungen
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The reaction of a combination of primary or secondary aromatic or aliphatic amines with orthocarboxylic esters upon a variety of open-chain CH2-acidic molecules gives N-substituted aminoalkylidene derivatives.The method is highly recommended for methylene
- Wolfbeis, Otto S.
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p. 3471 - 3484
(2007/10/02)
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- Cyanoacrylates. Herbicidial and Photosynthetic Inhibitory Activity
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Various alkyl 3-ohenylamino-2-cyano- and 2-ethoxycarbonylacrylates and 3-phenylamino-2-cyanoacrylonitriles were synthesized and assayed as inhibitors of the Hill reaction in isolated pea chloroplast suspensions and as pre- and post-emergent herbicides on mustard and barnyard grass.Many of the compounds were potent Hill reaction inhibitors and several showed significant herbicidial activity.
- Huppatz, John L.,Phillips, John N.,Rattigan, Barbara M.
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p. 2769 - 2774
(2007/10/02)
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- Herbicidal methods
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Herbicidal methods employing anilino compounds having the formula: EQU1 wherein R and R1 are selected from the group consisting of hydrogen and methyl; R2 and R3 are selected from the group consisting of CN and COOY, where Y is an alkyl group having from 1 to 8 carbon atoms; X is selected from the group consisting of lower alkyl having 1 to 4 carbon atoms, lower alkoxy having from 1 to 4 carbon atoms, nitro, trifluoromethyl, and halo; and n is an integer from 0 to 2, are disclosed.
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