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Anthracene, 9-(methoxymethyl)-, also known as 9-(methoxymethyl)anthracene or 9-methoxymethylanthracene, is an organic compound with the chemical formula C15H14O. It is a derivative of anthracene, a tricyclic aromatic hydrocarbon, with a methoxymethyl group (-OCH3) attached to the 9th carbon atom. Anthracene, 9-(methoxymethyl)- is characterized by its yellow crystalline appearance and is soluble in organic solvents. It is primarily used as a chemical intermediate in the synthesis of various pharmaceuticals, agrochemicals, and other organic compounds. Due to its potential applications in the production of dyes and pigments, it is also of interest in the chemical industry. However, like many other anthracene derivatives, it may have potential environmental and health concerns due to its chemical properties, and thus, proper handling and disposal are essential.

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  • 2584-79-4 Structure
  • Basic information

    1. Product Name: Anthracene, 9-(methoxymethyl)-
    2. Synonyms:
    3. CAS NO:2584-79-4
    4. Molecular Formula: C16H14O
    5. Molecular Weight: 222.287
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 2584-79-4.mol
    9. Article Data: 4
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Anthracene, 9-(methoxymethyl)-(CAS DataBase Reference)
    10. NIST Chemistry Reference: Anthracene, 9-(methoxymethyl)-(2584-79-4)
    11. EPA Substance Registry System: Anthracene, 9-(methoxymethyl)-(2584-79-4)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 2584-79-4(Hazardous Substances Data)

2584-79-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 2584-79-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,5,8 and 4 respectively; the second part has 2 digits, 7 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 2584-79:
(6*2)+(5*5)+(4*8)+(3*4)+(2*7)+(1*9)=104
104 % 10 = 4
So 2584-79-4 is a valid CAS Registry Number.

2584-79-4Relevant articles and documents

Competitive occurrence of homolytic N-O and heterolytic C-O bond cleavage in excited-state 1-(arylmethyloxy)-2-pyridones

Yoshioka, Nariyoshi,Andoh, Chihei,Kubo, Kanji,Igarashi, Tetsutaro,Sakurai, Tadamitsu

, p. 1927 - 1932 (2007/10/03)

The irradiation at 340 nm of the title compounds having 9-anthryl and pyren-1-yl groups in methanol was found to give the heterolytic C-O bond cleavage products: 1-hydroxy-2-pyridone and aryl-substituted dimethyl ether (which predominate for the reaction of the former title compound) in addition to 2-pyridone, aryl-substituted methanol and aryl-substituted formaldehyde derived from the homolysis of the N-O bond (which mainly occurs in the photolysis of the latter title compound). It was also found that substitution of the methyl group for hydrogen at the 6-position of the pyridone skeleton in 1-(9-anthrylmethyloxy)-2-pyridone decreases the relative composition of the arylsubstituted dimethyl ether to some extent. These substituent effects on the product compositions were explained in terms of stereoelectronic effects on a charge transfer-type interaction between the aromatic and pyridone rings in the singlet excited state. Analyses of the ground-state conformation for the title compounds by MM2 calculations and 1H NMR spectroscopy, as well as of their singlet excited-state behaviour, substantiated the existence of a non-emissive intramolecular exciplex intermediate which plays a key role in inducing the C-O bond heterolysis.

Photoinduced heterolysis of the carbon-oxygen bond in bichromophoric 1- arylmethyloxy-2-pyridones

Sakurai, Tadamitsu,Kubo, Kanji,Kojima, Shunsuke,Shoro, Takuya,Inoue, Hiroyasu

, p. 9747 - 9750 (2007/10/03)

Irradiation of the title compound having a 9-anthryl (1a) or a 1- pyrenyl group (1b) in methanol was found to give the heterolytic C-O bond cleavage products: 1-hydroxy-2-pyridone and arylmethyl methyl ether, (which predominate for the reaction of 1a), along with 2-pyridone, aryl-substituted methanol and aryl aldehyde derived from the homolysis of the N-O bond (that mainly occurs in the photolysis of 1b). Spectroscopic analysis of the ground- state and excited singlet-state behavior of 1 revealed that a non-emissive intramolecular exciplex (whose formation rate is much faster in 1a than in 1b) plays a key role in inducing the C-O bond heterolysis.

TELE-SUBSTITUTIONS EN SERIE ANTHRACENIQUE - II; EXTENSION DE LA SUBSTITUTION PAR L'ION PHENATE A DIVERS BROMO-9 ANTHRACENES MESO-ALKYLES

Rigaudy, J.,Seuleiman, A.M.,Cuong, Nguyen Kim

, p. 3151 - 3156 (2007/10/02)

A competition between normal substitution and tele-substitution is observed with 9-bromoanthracenes bearing in the opposite meso position an ethyl, 1b, or a benzyl group 1d.When treated with potassium phenoxide in HMPT these bromides afford mixtures of 9-alkyl-10-phenoxy-anthracenes 2 and 9-α(phenoxyalkyl) anthracenes 3.On the other hand 9-bromo-10 isopropylanthracene 1c is quite unreactive and 9-bromo-10-methoxymethylanthracene 1e leads essentyally to anthraldehyde 7.

TELE-SUBSTITUTIONS EN SERIE ANTHRACENIQUE-I. COMPORTEMENT DU BROMO-9-METHYL-10 ANTHRACENE VIS-A-VIS DES ANIONS PHENATES ET ALCOOLATES

Rigaudy, J.,Seuleiman, A.M.,Cuong, Nguyen Kim

, p. 3143 - 3150 (2007/10/02)

Treatment of 9-bromo-10-methyl anthracene 1, in dipolar aprotic solvents, by alkaline phenoxide or alkoxides leads essentially to a mixture of the expected ether, 9-phenoxy (or alkoxy)-10-methyl anthracene 2, normal substitution product (NSP), and of the isomeric ether, 9-phenoxymethyl (or alkoxymethyl)-anthracene 3, tele-substitution product (TSP).It is shown that both ethers must derive from a common unstable intermediate, the 9-bromo-10-methylene-9,10-dihydroanthracene 8, coming from 1 by a prototropic shift and which can undergo both types of substitution.With more hindered phenoxide ions, only the tele-substitution process is observed.

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