Performance of energy storage devices: potential areas for dendritic chemistry involvement
A compound consists of a fractal-like, plain or organometallic array useful for energy storage devices. A dendrimer useful in the synthesis of the fractal-like compound includes a single ligating moiety bound to a surface of each quadrant of the dendrimer. A method of making metallo-based (macro) molecules includes the steps of combining monomers selected from the group consisting of bipyridal- and terpyridal-based ligands with connecting metals and self assembling macrocycles wherein the monomes are interconnected by the metals.
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Page/Page column 10; sheet 7
(2008/06/13)
Hexagonal terpyridine-ruthenium and -iron macrocyclic complexes by stepwise and self-assembly procedures
Methods for the self-assembly, as well as directed construction, of hexaruthenium metallomacrocycles employing bisterpyridine building blocks are described. Self-assembly is effected by a combination of equimolar mixtures of bismetalated and nonmetalated
Newkome, George R.,Cho, Tae Joon,Moorefield, Charles N.,Cush, Randy,Russo, Paul S.,Godinez, Luis A.,Saunders, Mary Jane,Mohapatra, Prabhu
p. 2946 - 2954
(2007/10/03)
Self- and directed assembly of hexaruthenium macrocycles
Rigid terpyridine-based building blocks allow easy access to large polymetallomacrocycles (see picture) through a self-assembly process. Such routes are envisioned to provide one-step methods to higher order motifs and facilitate the creation of precisely organized, metal-based networks for new energy storage devices.
Newkome, George R.,Cho, Tae Joon,Moorefield, Charles N.,Baker, Gregory R.,Cush, Randy,Russo, Paul S.
p. 3717 - 3721
(2007/10/03)
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