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Iodo(p-tolyl)mercury(II), with the chemical formula Hg(C7H7)I, is a coordination complex where a mercury(II) ion is coordinated to an iodine atom and a p-tolyl group. This white, crystalline solid is insoluble in water but readily soluble in organic solvents. It is a significant compound in the realm of organic synthesis and catalysis.

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  • 26037-72-9 Structure
  • Basic information

    1. Product Name: Iodo(p-tolyl)mercury(II)
    2. Synonyms: Iodo(p-tolyl)mercury(II)
    3. CAS NO:26037-72-9
    4. Molecular Formula: C7H7 Hg I
    5. Molecular Weight: 418.63
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 26037-72-9.mol
    9. Article Data: 1
  • Chemical Properties

    1. Melting Point: 218-219 °C
    2. Boiling Point: 102.2°C
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Iodo(p-tolyl)mercury(II)(CAS DataBase Reference)
    10. NIST Chemistry Reference: Iodo(p-tolyl)mercury(II)(26037-72-9)
    11. EPA Substance Registry System: Iodo(p-tolyl)mercury(II)(26037-72-9)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 26037-72-9(Hazardous Substances Data)

26037-72-9 Usage

Uses

Used in Organic Synthesis:
Iodo(p-tolyl)mercury(II) is utilized as a reagent for the introduction of mercury and iodine into organic molecules. Its ability to facilitate the incorporation of these elements into complex organic structures makes it a valuable tool in the synthesis of various organic compounds.
Used in Catalysis:
In the field of catalysis, Iodo(p-tolyl)mercury(II) serves as a catalyst in certain chemical reactions. Its catalytic properties can enhance the efficiency and selectivity of specific chemical processes, contributing to the advancement of chemical research and industrial applications.
Used in Research:
Due to its unique properties and reactivity, Iodo(p-tolyl)mercury(II) is also employed in research settings to explore new chemical reactions and mechanisms, further expanding the understanding of mercury and iodine chemistry.
It is crucial to handle Iodo(p-tolyl)mercury(II) with caution due to its toxic nature, which can pose risks to human health and the environment if mismanaged. Proper safety measures and disposal methods must be strictly adhered to when working with this compound.

Check Digit Verification of cas no

The CAS Registry Mumber 26037-72-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,6,0,3 and 7 respectively; the second part has 2 digits, 7 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 26037-72:
(7*2)+(6*6)+(5*0)+(4*3)+(3*7)+(2*7)+(1*2)=99
99 % 10 = 9
So 26037-72-9 is a valid CAS Registry Number.
InChI:InChI=1/C7H7.Hg.HI/c1-7-5-3-2-4-6-7;;/h3-6H,1H3;;1H/q;+1;/p-1/rC7H7HgI/c1-6-2-4-7(8-9)5-3-6/h2-5H,1H3

26037-72-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name iodo-(4-methylphenyl)mercury

1.2 Other means of identification

Product number -
Other names WLN: I-HG-R D1

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:26037-72-9 SDS

26037-72-9Downstream Products

26037-72-9Relevant articles and documents

Substituent effects in aromatic substitution of aryltriethyltin compounds by mercuric halides

Sedaghat-Herati, M. Reza,Sharifi, Taghi

, p. 39 - 44 (2007/10/02)

Second-order rate constants are reported for the reaction of some YC6H4SnEt3 compounds with mercuric halides in tetrahydrofuran, and show that the reaction is one of low selectivity.The substituent effects can be correlated only in terms of Hammett ?-constants, and the data for the meta-methoxy group are anomalous.The results indicate that the rate determining step involves reaction of a ?-complex.Activation parameters are reported, and are in accordance with the suggested mechanism.

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