- Activation of Dithiocarbamate by 2-Halothiazolium Salts
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Activation of dithiocarbamate salts with 2-halo-3-alkyl-4-phenylthiazolium salt and subsequent one-pot nucleophilic reaction with N, S, and O nucleophiles provided substituted thioureas, dithiocarbamates, and thiocarbamates or amides, respectively, under very mild conditions.A useful thiocarbonyl-transfer reaction is also described that consists of activation of imidazolodithiocarbamate and a subsequent one-pot nucleophilic reaction. (Thiocarbonyl)diimidazole is generated in situ.
- Sugimoto, Hirohiko,Makino, Itsuo,Hirai, Kentaro
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p. 2263 - 2267
(2007/10/02)
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