- Synthesis and crystal structure determination of 2,2′-sulfinyl-bis(4- methyl phenol) and 2,2′-thio-bis(4-methyl phenol)
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2,2′-Sulfinyl-bis(4-methyl phenol) 3 and it's thio derivative have been synthesized in this work. The reduction process of sulfoxide 3 to its thio derivative 5 was accomplished in the presence of Zn/AcOH/SiO2, under microwave irradiation. The s
- Shockravi, Abbas,Alizadeh, Robabeh,Aghabozorg, Hossein,Moghimi, Abolghasem,Rostami, Esmael,Bavili, Samad
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- Synthesis of new benzosulfoxide macrocyclic compounds
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Bis(dibenzosulfoxo)-27,30,35,38-tetramethyl-24-crown-6, bis(dibenzosulfoxo)-21,24,29,32-tetramethyl-18-crown-4, dibenzosulfoxo-15,18- dimethyl-12-crown-3 and dibenzosulfoxo-12,15-dimethyl-9-crown-2 macrocycles are synthesized by the reaction of 2,2′-sulfi
- Shockravi, Abbas,Rostami, Esmael,Dehjurian, Ali,Tohidi, Rahim,Tohidi, Samad Bavili
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- Synthesis, crystal structure and magnetic properties of a trinuclear phenolate bridged manganese complex containing Mn(ii)-Mn(iii) ions
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A trinuclear manganese complex containing Mn(iii)-Mn(ii)-Mn(iii) cores, [Mn3(bp)4(CH3OH)]·0.875CH 3OH·0.125H2O (1), has been prepared and structurally characterized where H2bp is an O3
- Bikas, Rahman,Hosseini-Monfared, Hassan,Sanchiz, Joaquin,Siczek, Milosz,Lis, Tadeusz
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- Bench-Stable Sulfoxide-Based Boronates: Preparation and Application in a Tandem Suzuki Reaction
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A set of novel aromatic and heteroaromatic bench-stable sulfoxide-based boronates was prepared. The structure of the boronates was established by means of X-ray crystallography, and the prepared boronates were successively used in Suzuki cross-coupling reactions under different conditions. We also developed a tandem Suzuki reaction so that a base is generated during the nucleophilic addition of Grignard reagents to 4-bromobenzaldehyde. The formed intermediates were smoothly coupled with the prepared boronates and the boronic acids under external base-free conditions. (Figure presented.).
- ?ubiňák, Marek,Eigner, Václav,Tobrman, Tomá?
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p. 4604 - 4614
(2018/10/31)
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- Synthesis of some new ligands as drug carrier
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In this research work, the preparation of new biscrown ether and lariat ether compounds as cationic and molecular acceptor are reported. For this purpose first, sulfoxide (1) was prepared by reaction of p-cresol with SOCl 2 in 65 % yield. Then
- Mahmod, Nikkhoo-Amiry,Alami, Somaye,Ebadi, Abdol Ghaffar
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scheme or table
p. 4681 - 4683
(2012/03/09)
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- Spectrophotometric study of complexation of Tri-Aza dibenzosulfide and dibenzosulfoxide macrocyclic compounds with heavy metal ions
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The complexation reactions between 7,10,13-triaza-1-thia-4,16-dioxa-20,24- dimethyl-2,3;17,18-dibenzo-cyclooctadecane-6,14-dione (TTD) and 7,10,13-triaza-1-sulfoxo-4,16-dioxa-20,24-dimethyl-2,3;17,18-dibenzo- cyclooctadecane-6,14-dione (TSD) macrocycles w
- Mozaffari, Shahla,Chaloosi, Marzieh,Divsar, Faten,Abouzari-Lotf, Ebrahim,Bavili, Samad T.,Yousefi, Ali,Shockravi, Abbas
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p. 2439 - 2448
(2008/02/10)
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- New method for the preparation of o-aryloxyphenols: Pummerer-type rearrangement of ano-hydroxyaryl sulfoxide
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A facile two-step preparation of o-aryloxyphenols is described in which the key step is the intramolecular trapping of an α-keto sulfonium salt prepared by Pummerer rearrangement of a symmetrical o-hydroxyaryl sulfoxide to give an orthoquinone mono(monoth
- Jung,Jachiet,Khan,Kim
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p. 361 - 364
(2007/10/02)
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