- Palladium-Catalyzed Vinylation of Haloazulenes and Halotropolones with Olefins. Utility of the Heck Reaction in the Conjugated Carbon Chain Preparation
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The reactions of 3-iodotropolone with styrenes (styrene, p-methoxystyrene, and 2-vinylpyridine), methyl acrylate, and allylic compounds (methyl 3-butenoate, 3-butenenitrile, 1-allyl-3,4-dimethoxybenzene, and 1-allyl-3,4-methylenedioxybenzene) were carried
- Horino, Hiroshi,Asao, Toyonobu,Inoue, Naoto
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p. 183 - 190
(2007/10/02)
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- VINYLIC SUBSTITUTION ON TROPONOID CATALYZED BY PALLADIUM COMPLEXES, AND FORMATION OF NEW C-Pd ?-COMPLEXES OF TROPONOID
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The reaction of 3-, 4- and 5-halotropolones with olefins catalyzed by palladium(0) complex gave 3-, 4- and 5-(substituated vinyl)tropolones respectively.Similarly, 2-chlorotropone gave 2-styryltropones.Some tropolonyl- and troponylpalladium-?-complexes we
- Horino, Hiroshi,Inoue, Naoto,Asao, Toyonobu
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p. 741 - 744
(2007/10/02)
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