- A 6 - multi-alkyl - 1, 3, 5 - triazine compound and its synthetic method and application
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The invention relates to a 6 - multi-alkyl - 1, 3, 5 - triazine compound and its synthetic method and application. The 6 - multi-alkyl - 1, 3, 5 - triazine compound having the general formula (I) of the structure. Synthetic method comprises: the biguanide
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Paragraph 0068-0075
(2019/02/13)
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- Visible-Light-Promoted [5 + 1] Annulation Initiated by Electron-Donor-Acceptor Complexes: Synthesis of Perfluoroalkyl-s-Triazines
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A visible-light-promoted electron-donor-acceptor (EDA) complex-initiated [5 + 1] annulation between biguanides and perfluoroalkyl halides for the construction of perfluoroalkyl-s-triazines has been developed. It was found that both visible light and dioxygen in the air are favorable for the reaction. A radical-polar crossover mechanism was proposed, in which sequential SET, radical combination, HF elimination, electrocyclization, and aromatization are involved.
- Wang, Rui,Wang, Lili,Xu, Qin,Ren, Bao-Yi,Liang, Fushun
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supporting information
(2019/05/07)
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