RINGOEFFNUNG UND METALLIERUNG VON 1,1-DIMETHYL-2-PHENYL-SILACYCLOPENTAN UNTER DEM EINFLUSS VON METHYLLITHIUM IN TETRAHYDROFURAN
In contrast to 1-phenylethyllithium, which reacts as a base, methyllithium attacks the silicon atom of 1,1-dimethyl-2-phenyl-silacyclopentane (7) as a nucleophile whereby ring-opening takes place presumably via an ate-complex intermediate.The primarily fo
Maercker, Adalbert,Stoetzel, Reinhard
p. C40 - C46
(2007/10/02)
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