- A convenient method for palladium-catalyzed reductive deuteration of organic substrates using deuterated hypophosphite in D2O
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A convenient method for the deuteration of organic substrates using deuterated hypophosphite as the deuterium source was investigated. Transfer deuteration of organic substrates, such as aromatic halides, alkenes, alkynes, epoxides, and O-benzyl derivativ
- Oba, Makoto
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p. 215 - 219
(2015/05/20)
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- Solid phase synthesis of selectively deuterated arenes
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A novel access to deuterated and D3CO-substituted arenes has been developed using immobilized triazenes as precursors. The linker system and the deuterating cleavage methodology could be shown to be compatible with various functional groups and are therefore suitable for the synthesis of derivatives only hardly available via comparable protocols.
- Vanderheiden, Sylvia,Bulat, Bekir,Zevaco, Thomas,Jung, Nicole,Braese, Stefan
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supporting information; experimental part
p. 9063 - 9065
(2011/09/19)
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