cas 327-76-4, 2,4-BIS(TRIFLUOROMETHYL)CHLOROBENZENE | Articles data ｜lookchem

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327-76-4

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Efficient copper-catalyzed trifluoromethylation of aromatic and heteroaromatic iodides: The beneficial anchoring effect of borates
Efficient copper-catalyzed trifluoromethylation of aromatic iodides was achieved with TMSCF3 in the presence of trimethylborate. The Lewis acid was used to anchor the in situ generated trifluoromethyl anion and suppress its rapid decomposition. Broad applicability of the new trifluoromethylating reaction was demonstrated in the functionalization of different aromatic and heteroaromatic iodides.
Gonda, Zsombor,Kovacs, Szabolcs,Weber, Csaba,Gati, Tamas,Meszaros, Attila,Kotschy, Andras,Novak, Zoltan
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p. 4268 - 4271
(2014/09/30)

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Chemical Properties

Melting Point: -59 - -58 °C
Boiling Point: 149.9 °C at 760 mmHg
Flash Point:56.6 °C
Density: 1.475 g/cm³
Storage Temp.:2-8°C
Refractive Index: 1.4140
BRN: 1978012
PSA: 0.00000
LogP: 4.37760

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