- Heavy cyclopropene analogues R4SiGe2 and R4Ge3 (R = SiMetBu2) - New members of the cyclic digermenes family
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1H-Siladigermirene R4SiGe2 (2a) and 1H-trigermirene R4Ge3 (2b) (R = SiMetBu2) with a Ge{double bond, long}Ge double bond were synthesized by the reaction of tetrachlorodigermane RGeCl2-GeCl2R with dilithiosilane R2SiLi2 and dilithiogermane R2GeLi2, respectively. The skeletal Ge{double bond, long}Ge double bond of 2a is trans-bent (51.0(2)°) with a bond distance of 2.2429(6) A?. The reaction of both 2a and 2b with CH2Cl2 resulted in the formation of unusual four-membered ring compounds 5a and 5b as a result of a ring expansion reaction. 1H-Trisilirene 7a and 3H-disilagermirene 7b with an Si{double bond, long}Si double bond also smoothly reacted with CH2Cl2 to yield the four-membered ring systems 8a and 8b, respectively.
- Lee, Vladimir Ya.,Yasuda, Hiroyuki,Ichinohe, Masaaki,Sekiguchi, Akira
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- The acidities of some aryl-substituted germanes in liquid ammonia
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Proton magnetic resonance techniques have been used to determine the acidities of some aryl-substituted germanes in liquid ammonia. It was found that increasing aryl substitution caused a reduction in acidity. Factors such as solvation, ion pairing, and structural effects are used to explain the order of acidities.
- Birchall,Drummond
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p. 250 - 252
(2007/10/05)
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