Reduction of olefins using ruthenium carbene catalysts and silanes
Ruthenium carbene complexes are able to mediate reduction of olefins in the presence of trialkylsilanes. Under these reduction conditions, when kinetically favorable ring-closing metathesis is possible, a one-pot cyclization-reduction sequence can be performed. Georg Thieme Verlag Stuttgart.
Menozzi, Candice,Dalko, Peter I.,Cossy, Janine
p. 2449 - 2452
(2007/10/03)
CONVERSION OF METHYLENEDIOXYBENZENE DERIVATIVES INTO 2-METHOXYPHENOL DERIVATIVES
Methylenedioxybenzene derivatives are reductively cleft with diisobutylaluminum hydride to give 2-methoxyphenol derivatives.Concurrent hydroalumination occures when a substrate contains an olefinic bond in a side chain.
Takano, Seiichi,Akiyama, Masashi,Ogasawara, Kunio
p. 2237 - 2238
(2007/10/02)
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