- Nitrophenyl derivatives of pyrrole 2,5-diamides: Structural behaviour, anion binding and colour change signalled deprotonation
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Two new pyrrole 2,5-diamide clefts have been synthesized containing 4-nitrophenyl or 3,5-dinitrophenyl groups appended to the amide positions. The 3,5-dinitrophenyl derivative has been shown to deprotonate in the presence of fluoride, which in acetonitride solution, gives rise to a deep blue colour.
- Camiolo, Salvatore,Gale, Philip A.,Hursthouse, Michael B.,Light, Mark E.
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Read Online
- A dual host approach to NiSO4 extraction
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This paper reports the synthesis of sulphate extractants, N,N-bis-(2-dibutylamino-ethyl)-isophthalamide (1), pyridine-2,6-dicarboxylic acid bis-[(2-dibutylamino-ethyl)-amide] (2) and 3,4-diphenyl-1H-pyrrole-2,5- dicarboxylic acid bis-[(2-dibutylamino-ethy
- Bates, Gareth W.,Davidson, James E.,Forgan, Ross S.,Gale, Philip A.,Henderson, David K.,King, Michael G.,Light, Mark E.,Moore, Stephen J.,Tasker, Peter A.,Tong, Christine C.
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experimental part
p. 117 - 126
(2012/06/30)
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- Amidopyrroles: From anion receptors to membrane transport agents
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Amidopyrroles have been employed in a variety of anion receptors and sensors. 2,5-Bisamidopyrroles show selective oxo-anion complexation properties in organic solution whilst bis-amides containing dipyrrolylmethane groups form strong complexes with dihydr
- Gale, Philip A.
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p. 3761 - 3772
(2007/10/03)
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- Hydrogen-bonding pyrrolic amide cleft anion receptors
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The use of simple 2,5-diamidopyrrole derivatives as anion receptors has been investigated. Reaction of 3,4-diphenylpyrrole-2,5-dicarboxylic acid chloride with n-butylamine or aniline has produced two new amidic cleft anion receptors 1 and 2. The anion-coo
- Gale, Philip A.,Camiolo, Salvatore,Chapman, Christopher P.,Light, Mark E.,Hursthouse, Michael B.
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p. 5095 - 5097
(2007/10/03)
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- 2-Amidopyrroles and 2,5-diamidopyrroles as simple anion binding Agents
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Four new 2-amidopyrroles and 2,5-diamidopyrroles have been synthesized and their anion complexation properties investigated. The crystal structures of these receptors have been elucidated and reveal hydrogen bonding in the solid state leading to dimer and network formation. Selectivity for oxo-anions has been demonstrated by 1H NMR titration techniques.
- Gale,Camiolo,Tizzard,Chapman,Light,Coles,Hursthouse
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p. 7849 - 7853
(2007/10/03)
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