- Nickel-Catalyzed Reductive Cross-Coupling of Aryl Bromides with Vinyl Acetate in Dimethyl Isosorbide as a Sustainable Solvent
-
A nickel-catalyzed reductive cross-coupling has been achieved using (hetero)aryl bromides and vinyl acetate as the coupling partners. This mild, applicable method provides a reliable access to a variety of vinyl arenes, heteroarenes, and benzoheterocycles, which should expand the chemical space of precursors to fine chemicals and polymers. Importantly, a sustainable solvent, dimethyl isosorbide, is used, making this protocol more attractive from the point of view of green chemistry.
- Su, Mincong,Huang, Xia,Lei, Chuanhu,Jin, Jian
-
supporting information
p. 354 - 358
(2022/01/15)
-
- A general and efficient heterogeneous gold-catalyzed hydration of nitriles in neat water under mild atmospheric conditions
-
Mild, efficient and general: Titania decorated with nanometer-sized gold particles acts as an efficient catalyst for the selective hydration of a wide range of chemically diverse nitriles into valuable amides in neutral water, under mild atmospheric conditions (see image). The process shows promise for a facile and direct one-pot synthesis of ?μ-caprolactam, an industrially important molecule, starting from 6-aminocapronitrile. Copyright
- Liu, Yong-Mei,He, Lin,Wang, Miao-Miao,Cao, Yong,He, He-Yong,Fan, Kang-Nian
-
scheme or table
p. 1392 - 1396
(2012/10/07)
-
- Formation of Carbon-Carbon Bond on Solid Support: Application of the Stille Reaction
-
Vinyl/Aryl stannanes couple smoothly with polymer bound aryl iodides.The cross-coupled products are obtained in excellent yield and purity after cleavage from the solid support.
- Deshpande, Milind S.
-
p. 5613 - 5614
(2007/10/02)
-