Liquid-phase isomerization of saturated and unsaturated epoxides
The liquid-phase isomerization of a variety of epoxides was studied using a complex catalyst system based on magnesium bromide and dimethylformamide. The data obtained elucidate the mechanism of the liquid-phase isomerization and show the range of oxygen-containing compounds which can be prepared through this reaction.
Mel'nik,Khvatova,Moskvichev,Srednev,Egorova
p. 167 - 169
(2007/10/03)
Clemmensen Reduction. XI. Fragmentation Reactions of Some 3-Acetylcycloalkanones
Clemmensen reduction of a series of 3-acetylcycloalkanones yields, as the major product, an acyclic unsaturated ketone, the product of fragmentation.Some normal carbonyl-methylene reduction also occurs.A mechanistic rationale for the fragmentation is advanced.
Bailey, Karen E.,Davis, Brian R.
p. 1827 - 1834
(2007/10/03)
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