- REACTIONS OF SULFUR DIOXIDE WITH AMINOPHOSPHINES
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The reactions of SO2 with tris-dimethylaminophosphine, bis-dimethylaminofluorophosphine, bis-dimethylaminochlorophosphine, dimethylaminodifluorophosphine, dimethylaminodichlorophosphine, 1,3-dimethyl-2-fluoro-1,3,2-diazaphospholidine and 1,3-dimethyl-2-chloro-1,3,2-diazaphospholidine have been investigated.The complex reactions are dominated by facile oxidation of the respective phosphine to phosphoryl and thiphosphoryl derivatives.The new heterocyclic phosphines CH3(O)F and CH3(S)F have been isolated and characterized by NMR, infrared, and mass spectrometry.
- Light, R. W.,Paine, R. T.
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p. 255 - 258
(2007/10/02)
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