Decarboxylative Borylation of mCPBA-Activated Aliphatic Acids
A decarboxylative borylation of aliphatic acids for the synthesis of a variety of alkylboronates has been developed by mixing m-chloroperoxybenzoic acid (mCPBA)-activated fatty acids with bis(catecholato)diboron in N,N-dimethylformamide (DMF) at room temperature. A radical chain process is involved in the reaction which initiates from the B-B bond homolysis followed by the radical transfer from the boron atom to the carbon atom with subsequent decarboxylation and borylation.
Wei, Dian,Liu, Tu-Ming,Zhou, Bo,Han, Bing
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p. 234 - 238
(2020/01/02)
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