cas 39745-40-9, 3-AMINO-2-CHLORO-6-PICOLINE | Articles data ｜lookchem

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39745-40-9

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Molecular structure and spectroscopic properties of new neodymium complex with 3-bromo-2-chloro-6-picolinic N-oxide showing the ligand-to-metal energy transfer
A new neodymium [Nd(BCPN)3(NO3)3(H2O)2] complex with 3-bromo-2-chloro-6-picolinic N-oxide was synthesized and characterized by means of spectroscopic studies and DFT quantum chemical calculations. The IR, Raman, electron UV-VIS and emission spectra measurements were performed. The femtosecond excitation was used to establish an excited energy level depopulation mechanism. The influence of the halo-groups position on the structural and optical properties of the studied compound was discussed. Ligand-to-metal energy transfer in the studied neodymium complex was analysed.
Hanuza, Jerzy,Lisiecki, Rados?aw,Lorenc, Jadwiga,Macalik, Lucyna,S?siadek, Wojciech,Wandas, Maria
(2021)
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Synthesis of dihalopicoline N-oxides and their 4-nitro derivatives
Three aminohalo-substituted α- and β-picolines, six dihalo-substituted α- and β-picolines, six dihalo-substituted α- and β-picoline N-oxides and six respective dihalo-4-nitropicoline N-oxides were synthesized in excellent yields. Some properties of the products were reported. 1997 Plenum Publishing Corporation.
Ciurla,Puszko
p. 1173 - 1177
(2007/10/03)

2-Phenyl-3H-imidazopyridine-3-acetamides as Non-Benzodiazepine Anticonvulsants and Anxiolytics
A series of 2-phenyl-3H-imidazopyridine-3-acetamides were designed and synthesized as non-benzodiazepine anxiolytics based on a molecular disconnection of a typical 1,4-benzodiazepine (BZD).A number of these compounds showed submicromolar potency i
Tomczuk, Bruce E.,Taylor, C. R,Moses, L. Meredith,Sutherland, Deborah B.,Lo, Young S.,et al.
p. 2993 - 3006
(2007/10/02)

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Chemical Properties

Appearance/Colour :Light yellow cryst.
Melting Point: 88-91 °C
Boiling Point: 262.3 °C at 760 mmHg
Flash Point:112.5 °C
Density: 1.26 g/cm³
Storage Temp.:under inert gas (nitrogen or Argon) at 2–8 °C
Vapor Pressure: 0.011mmHg at 25°C
Refractive Index: 1.592
PKA: 3.38±0.10(Predicted)
PSA: 38.91000
LogP: 2.20680

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