Tunable Prussian blue analogues for the selective synthesis of propargylamines through A3 coupling
M1[Co(CN)6]2/3-type Prussian blue analogues (M1-Co PBAs) were studied as catalysts for the synthesis of propargylamines via A3 coupling of phenylacetylene, benzaldehyde and piperidine. Cu0.86/su
Marquez, Carlos,Cirujano, Francisco G.,Van Goethem, Cédric,Vankelecom, Ivo,De Vos, Dirk,De Baerdemaeker, Trees
p. 2061 - 2065
(2018/05/03)
Hydrogen peroxide mediated efficient amidation and esterification of aldehydes: Scope and selectivity
An efficient method for the amidation and esterification of aldehydes utilizing hydrogen peroxide as an oxidant has been developed. Cyclic amines and primary alcohols selectively reacted with aromatic aldehydes under mild conditions to yield the corresponding amides and esters.
One-step three-component coupling of aromatic organozinc reagents, secondary amines, and aromatic aldehydes into functionalized diarylmethylamines
Numerous functionalized diarylmethylamines have been synthesized in high yield according to a one-step three-component coupling between an aromatic organozinc reagent, a secondary amine, and an aromatic aldehyde. Both organozinc species and aldehyde can bear a functional group and either aromatic or non-aromatic amines can be used in this versatile procedure.
Le Gall, Erwan,Troupel, Michel,Nédélec, Jean-Yves
p. 9953 - 9965
(2007/10/03)
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