Formation of Chiral Allylic Ethers via an Enantioselective Palladium-Catalyzed Alkenylation of Acyclic Enol Ethers
This report details a palladium-catalyzed process to access highly functionalized, optically active allylic aryl ethers. A number of electron-deficient alkenyl triflates underwent enantioselective and site-selective coupling with acyclic aryl enol ethers
Patel, Harshkumar H.,Prater, Matthew B.,Squire, Scott O.,Sigman, Matthew S.
supporting information
p. 5895 - 5898
(2018/05/14)
Synthetic and computational studies of acyl radical cyclizations with β-alkoxyacrylates: Formal synthesis of (±)-longianone
An investigation into the cyclization of acyl radicals with mono- and disubstituted β-alkoxyacrylates is described. Ether-tethered acyl radicals, generated directly from the corresponding aldehyde, undergo cyclization to form dioxaspiro heterocyclic syste
Aitken, Heather M.,Schiesser, Carl H.,Donner, Christopher D.
scheme or table
p. 409 - 415
(2011/10/09)
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