REACTION OF ALKYL THIOCYANATES WITH AMIDOPHOSPHITES AND PHOSPHONITES
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Kamalov, R. M.,Stepanov, G. S.,Gol'dfarb, E. I.,Ryzhikov, D. V.,Pudovik, M. A.,Pudovik, A. N.
p. 306 - 309
(2007/10/02)
CHEMICAL PROPERTIES OF TETRAALKYLPHOSPHORODIAMIDOUS IODIDES AND TETRAALKYLPHOSPHORODIAMIDOTHIOIC IODIDES
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Mitel'man, I. E.,Gorbatenko, Zh. K.,Feshchenko, N. G.
p. 1114 - 1119
(2007/10/02)
Desulfurization of Organic Trisulfides by Tris(dialkylamino)phosphines. Mechanistic Aspects
Tris(dialkylamino)phosphines effect a rapid desulfurization of trisulfides to disulfides under mild conditions.The reaction mechanism involves a bimolecular process, proceeding by the rate-determining formation of a phosphonium salt intermediate.The central sulfur atom of a diaryl trisulfide is removed in the process, while a dialkyl trisulfide loses a terminal sulfur atom to the aminophosphine.
Harpp, David N.,Ash, David K.,Smith, Roger A.
p. 5155 - 5160
(2007/10/02)
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