- Steric effects in the catalytic amination of γ-, δ-, and ε-glycols
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The amination of butane-1,4-diol, isomeric dipropylene glycols, and cyclohexane-1,4-diyldimethanol in the presence of nickel/copper/chromium catalysts has been studied. The effect of the initial glycol structure on the reaction selectivity has been estima
- Timofeev,Bazanov,Zubritskaya
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p. 1756 - 1761
(2017/02/19)
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- Activity of copper- and iron-containing catalysts in the reaction of diols with ammonia in the presence of hydrogen
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An investigation has been made of the vapour-phase reaction of 1,4-butanediol, 1,5-pentadiol, 1,6-hexanediol and 2,5-hexanediol with ammonia and hydrogen at a temperature of 160-230°C on oxide copper-zinc-aluminium catalyst SNM-1 and a reduced, promoted, sintered iron catalyst. The composition of the main reaction products has been established, and schemes of their formation are suggested.
- Shuikin,Glebov,Kliger,Zaikin
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- SYNTHESIS OF NITROGEN-CONTAINING HETEROCYCLES OF AN IRON CATALYST. 2. THE CONVERSIONS OF 1,4-BUTANEDIOL AND DIETHYLENEGLYCOL IN THE PRESENCE OF AMMONIA AND HYDROGEN
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The gas-phase interaction of 1,4-butanediol and diethylene glycol with ammonia and/or hydrogen on a reduced, fused, iron catalyst has been investigated.
- Kliger, G. A.,Lesik, O. A.,Marchevskaya, E. V.,Mikaya, A. I.,Zaikin, V. G.,et al.
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p. 161 - 164
(2007/10/02)
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