- Synthesis of new 2-(alkenylsulfanyl)pyrimidine derivatives
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Isothiuronium salts prepared by treatment of allyl bromide, 2,3- and 1,3-dichloropropenes, and 1,3-dichlorobut-2-ene with thiourea reacted with pentane-2,4-dione and 4,4,4-trifluoro-1-(thiophen-2-yl)-butane-1,3-dione to afford new pyrimidine derivatives, 2-(alkenylsulfanyl)-4,6-dimethyl- and 2-(alkenylsulfanyl)-4-(thiophen-2-yl)-6-(trifluoromethyl)pyrimidines.
- Levanova,Grabel'nykh,Vakhrina,Russavskaya,Albanov,Korchevin,Rozentsveig
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p. 429 - 433
(2014/06/09)
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- Matrix isolation and spectroscopic properties of the methylsulfinyl radical CH3(O)S
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The atmospherically highly relevant methylsulfinyl radical CH 3(O)S was generated thermally under flash pyrolysis conditions and isolated in Ar matrices at 10 K; the allyl radical is a byproduct. CH 3(O)S and its D3- and 13C-isotopologues were characterized through the excellent agreement between experimental and computed IR and UV/Vis spectra.
- Reisenauer, Hans Peter,Romanski, Jaroslaw,Mloston, Grzegorz,Schreiner, Peter R.
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supporting information
p. 9467 - 9469
(2013/10/01)
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