Three different radical reactions were used in a short total synthesis of (±)-matrine (1). Two of the four six-membered rings and four new bonds were created in one radical cascade involving intermolecular addition followed by two successive cyclizations and transfer of a xanthate group.
Boiteau, Laurent,Boivin, Jean,Liard, Annie,Quiclet-Sire, Beatrice,Zard, Samir Z.
p. 1128 - 1130
(2007/10/03)
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