The first structurally characterized aluminum compound with two SH groups: [LAI(SH)2] (L = N(Ar)C(Me)CHC(Me)N(Ar), Ar = 2,6-i-Pr2C6H3) and the catalytic properties of the sulfur P(NMe2)3 system
Surprisingly stable is the bis(hydrogen sulfide) of aluminum LAl(SH)2 with two terminal arranged SH groups. The insertion of sulfur into the Al-H bonds is catalyzed by SP(NMe2)3. A possible mechanism is discussed. Copyright
Jancik, Vojtech,Peng, Ying,Roesky, Herbert W.,Li, Jiyang,Neculai, Dante,Neculai, Ana M.,Herbst-Irmer, Regine
Preparation of [LAI-(μ-S)2MCp2] (M = Ti, Zr) from the structurally characterized lithium completes [{LAl(SH)[SLi(thf) 2]}2] and [{LAI[SLi)2(thf)3] ·2-THF
Sulfur bridges: The reactions of [LAI(SH)2] (L = HC(CMeNAr) 2, Ar= 2,6-iPr2C6H3) with LiN(SiMe3)2 in molar ratio 1:2 and 1:1, respectively, lead to species with the formula [{LAl
Jancik, Vojtech,Roesky, Herbert W.,Neculai, Dante,Neculai, Ana M.,Herbst-Irmer, Regine
p. 6192 - 6196
(2007/10/03)
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