cas 51308-99-7, 9-Chloro-1-nonanol | Articles data ｜lookchem

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51308-99-7

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Oxidation of monohydric and dihydric alcohols with CCl4 catalyzed by molybdenum compounds
Mo(CO)6 catalyzed oxidation of alcohols and diols with tetrachloromethane. Primary oxidation products in reaction of alcohols with CCl4 are alkyl hypochlorites, and final products depending on the structure of initial alcohol are aldehydes (as acetals), ketones, chloroketones, and esters.
Khusnutdinov,Shchadneva,Burangulova,Muslimov,Dzhemilev
p. 1615 - 1621
(2007/10/03)

REGIOSPECIFIC AND STEREOSPECIFIC SUBSTITUTION OF HYDROXYL IN ALIPHATIC ALCOHOLS BY HALOGEN
A new system containing triphenylphosphine and trichloro- and tribromoacetic ester makes it possible to substitute the hydroxyl group in alcohols by halogen.Regiospecific and stereospecific substitution of the hydroxyl by the halogen takes place as a result of the reaction of primary and secondary aliphatic alcohols and of 2-alkenols, susceptible to isomerization processes, with this system.
Matveeva, E. D.,Kurts, A. L.,Yalovskaya, A. I.,Nikishova, N. G.,Bundel', Yu. G.
p. 642 - 646
(2007/10/02)

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Chemical Properties

Melting Point: 28°C
Boiling Point: 254.7 °C at 760 mmHg
Flash Point:114.1 °C
Density: 0.96 g/cm³
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C
Vapor Pressure: 0.0026mmHg at 25°C
Refractive Index: 1.451
PKA: 15.19±0.10(Predicted)
PSA: 20.23000
LogP: 2.94820

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