Tosylmethylamines as "Nonstabilized" α-Aminocarbanion Synthon Equivalents: Advantages and Limitations
Tosylmethylamines (1) are advantageous synthon equivalents for "nonstabilized" α-aminocarbanions of aromatic amines. Clean reactions and high yields are observed provided one-step procedures are utilized: the intermediate "nonstabilized" α-aminocarbanions are of low stability. Reactions formally involving dianions from bis(tosylmethyl)-substituted amines have also been achieved.
Katritzky, Alan R.,Feng, Daming,Qi, Ming
p. 6222 - 6225
(2007/10/03)
Note on synthesis of α amino and α amido sulfones. V: Sulfones as chemical forms of transport of germicidally acting substances
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Messinger,Gompertz
p. 653 - 655
(2007/10/11)
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