- The Photochemical Reaction of Benzocinnoline. IV. Comments on the Mechanism of 2,2'-Diaminobiphenyl Formation
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In order to determine the mechanism of 2,2'-diaminobiphenyl formation from benzocinnoline, effect of aldehyde on the reaction was examined.It is proposed that ethanal, which was generated from ethanol in the initial photoreduction, formed an adduct with 5,6-dihydrobenzocinnoline, and that the resulting adduct participated in the subsequent photo-induced 2,2'-diaminobiphenyl formation.
- Inoue, Hiroyasu,Hiroshima, Yukimi,Sakai, Toshihiko,Sakurai, Tadamitsu,Fukuda, Norio
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p. 2829 - 2830
(2007/10/02)
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