Total Synthesis and Stereochemical Confirmation of Heliolactone
Until now, the relative stereochemistry of the noncanonical strigolactone, heliolactone, has remained ambiguous. The total synthesis of heliolactone is described, with the key bond-forming event being a Stille cross-coupling that relied upon a reversal of
Woo, Stone,McErlean, Christopher S. P.
p. 4215 - 4218
(2019/06/04)
Synthesis and anti-metastatic effects of novel chiral ionone alkaloid derivatives
Abstract Novel chiral ionone alkaloid derivatives were synthesized and evaluated their anti-metastatic effects in human MDA-MB-231 breast cancer cells. The chiral center C-6 of derivatives exerted an important role in response to the anti-metastatic activ
Fang, Hai-Jun,Shou, Xiao-Ai,Liu, Qian,Gan, Chun-Chun,Duan, Hong-Quan,Qin, Nan
p. 245 - 253
(2015/07/08)
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