Aminocyanation by the addition of N-CN bonds to arynes: Chemoselective synthesis of 1,2-bifunctional aminobenzonitriles
An efficient aminocyanation by the direct addition of aryl cyanamides to arynes is described, enabling incorporation of highly useful amino and cyano groups synchronously via cleavage of inert N-CN bonds, affording synthetically useful 1,2-bifunctional aminobenzonitriles. The postsynthetic functionalization of the aminocyanation products allows diverse formation of synthetically important derivatives such as drug molecule Ponstan and fused heterocycles.
Rao, Bin,Zeng, Xiaoming
supporting information
p. 314 - 317
(2014/01/23)
A new procedure for the preparation of substituted ureas, acylureas, and sulfonylureas
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Anatoi,Berecoechea
p. 111 - 113
(2007/10/13)
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