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57294-38-9

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PHOTOLYTIC COMPOUNDS AND TRIPLET-TRIPLET ANNIHILATION MEDIATED PHOTOLYSIS
The invention provides novel photolytic compounds and prodrugs, nanoparticles and compositions thereof, and methods of conducting photolysis mediated by triplet-triplet annihilation.
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Paragraph 0026

(2021/04/17)

Ruthenium tetroxide oxidation of cyclic N-acylamines by a single layer method: formation of ω-amino acids
The ruthenium tetroxide oxidation of cyclic N-acyl amines by a 10% NaIO4 aqueous solution containing tert-butanol as a single layer system resulted in the endo-cyclic C-N bond cleavage to afford the ω-amino acids as almost sole products in good yields, while a similar oxidation under the double layer using a NaIO4 aqueous solution, and ethyl acetate gave the N-acyl lactams.
Kaname, Mamoru,Yoshifuji, Shigeyuki,Sashida, Haruki
p. 2786 - 2788
(2008/09/19)

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Chemical Properties

Appearance/Colour :White crystalline powder
Melting Point: 55-59 °C
Boiling Point: 78-82 °C0.2 mm Hg(lit.)
Flash Point:113 ºC
Density: 1.104g/cm³
Solubility:soluble in Methanol
Storage Temp.:2-8°C
Vapor Pressure: 4.4E-06mmHg at 25°C
Refractive Index: 1.4315 (estimate)
PKA: 4.70±0.10(Predicted)
BRN: 1869578
PSA: 75.63000
LogP: 1.76680

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