Deprotonation of aryl methanedithioate by lithium amides: Formation of lithium arylthio(thioxo)methanide having unique reactivity
Deprotonation of aryl methanedithioate 5 bearing a bowl-type bulky subsituent with lithium tetramethylpiperidide at low temperature gave organolithium species 9 which was in equilibrium with a dimeric species 10; 9 extruded C=S at higher temperatures, thu
Studies on the Reactivity of Carbon Monosulfide toward Amines and Thiols
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Moltzen, Ejner K.,Kramer, Michael P.,Senning, Alexander,Klabunde, Kenneth J.
p. 1156 - 1161
(2007/10/02)
Reactions of Thiophene and Alkylthiophenes in Glow Discharge
The glow discharge reaction of thiophene is shown to produce thioketene and carbon monosulfide along with other gaseous products.The dominant liquid product is ethynylthiophene.Methylthiophenes and especially dimethylthiophenes produce benzene as one of the major liquid products.
Skramstad, Jan,Chaudhry, Mohammed Shoaib,Garvang, Arne
p. 509 - 512
(2007/10/02)
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