1'-Derivatives of Sucrose and Their Acid Hydrolysis
Syntheses of 1'-chloro-1'-deoxy- and 1'-deoxy-sucrose are described.Several routes were investigated, the most successful being through 6,1',6'-tri-O-(2,4,6-trimethylbenzenesulfonyl)sucrose.Attempts to prepare 1'-deoxy-1'-fluorosucrose were unsuccessful.The rates of the acid-catalysed hydrolysis of 1'-chloro-1'-deoxysucrose and of 1'-deoxysucrose have been measured.These values are compared with that for sucrose itself.The mechanism of the hydrolyses is discussed.
Guthrie, R. D. (Gus),Jenkins, Ian D.,Watters, James J.
p. 2487 - 2497
(2007/10/02)
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