A single-step one pot synthesis of dialkyl fluorophosphates from dialkylphosphites
An efficient synthetic method has been developed to obtain dialkyl fluorophosphates from dialkylphosphites using inorganic reagent (CuCl2 and CsF) at room temperature.
Purohit, Ajay Kumar,Pardasani, Deepak,Kumar, Ajeet,Goud, D. Raghavender,Jain, Rajiv,Dubey
p. 4593 - 4595
(2015/07/08)
Single step fluorination of dialkylphosphites: trichloroacetonitrile-KF as an efficient reagent for the synthesis of dialkyl fluorophosphates
The use of trichloroacetonitrile and KF mixture is described as an efficient reagent for the direct conversion of dialkylphosphites to their corresponding dialkyl fluorophosphates via in situ formation of dialkyl chlorophosphates in one-pot.
Gupta,Acharya,Pardasani,Dubey
p. 2232 - 2235
(2008/09/19)
Trichloroisocyanuric acid-KF as an efficient reagent for one-pot synthesis of dialkylfluorophosphates from dialkylphosphites
Trichloroisocyanuric acid-KF afforded dialkylfluorophosphates from dialkylphosphites at room temperature through a facile electrophilic- nucleophilic metathesis. Copyright Taylor & Francis Group, LLC.