- GASOLINE PREPARED FROM BIOMASS-DERIVED LEVULINIC ACID
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The present invention provides methods for preparing a C6-C10 alkane, and mixture thereof. The methods include forming a reaction mixture containing an angelica lactone dimer, a catalyst, and a hydrogen source under conditions sufficient to reduce the angelica lactone dimer, thereby preparing the alkane. The methods can be used to prepare branched alkanes useful for fuels. Methods for preparing an angelica lactone, methods for preparing an angelica lactone dimer, and methods for reducing a lactone to an alkane are also described.
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Paragraph 0097
(2015/06/03)
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- Hydrodeoxygenation of the angelica lactone dimer, a cellulose-based feedstock: Simple, high-yield synthesis of branched C7-C10 gasoline-like hydrocarbons
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Dehydration of biomass-derived levulinic acid under solid acid catalysis and treatment of the resulting angelica lactone with catalytic K 2CO3 produces the angelica lactone dimer in excellent yield. This dimer serves as a novel feedstock for hydrodeoxygenation, which proceeds under relatively mild conditions with a combination of oxophilic metal and noble metal catalysts to yield branched C7-C10 hydrocarbons in the gasoline volatility range. Considering that levulinic acid is available in >80 % conversion from raw biomass, a field-to-tank yield of drop-in, cellulosic gasoline of >60 % is possible. Fuel for thought: Biomass-derived levulinic acid can be converted in three simple steps via the angelica lactone dimer into branched, gasoline-range hydrocarbons in high yield by using a combination of oxophilic metal and noble metal catalysts (see scheme). Copyright
- Mascal, Mark,Dutta, Saikat,Gandarias, Inaki
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supporting information
p. 1854 - 1857
(2014/03/21)
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- Impact of cationic surfactant chain length during SAPO-11 molecular sieve synthesis on structure, acidity, and n-octane isomerization to di-methyl hexanes
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The structure, acidity, and n-octane di-branched isomerization of SAPO-11 synthesized with surfactants of different chain lengths in water-propanol system were investigated. The results showed that with the increasing chain length of surfactants, the crys
- Guo, Lin,Bao, Xiaojun,Fan, Yu,Shi, Gang,Liu, Haiyan,Bai, Danjiang
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p. 161 - 170
(2012/11/07)
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- Ring opening of decalin via hydrogenolysis on Ir/- and Pt/silica catalysts
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The catalytic conversion of cis-decalin was studied at a hydrogen pressure of 5.2 MPa and temperatures of 250-410 °C on iridium and platinum supported on non-acidic silica. The absence of catalytically active Br?nsted acid sites was indicated by both FT-IR spectroscopy with pyridine as a probe and the selectivities in a catalytic test reaction, viz. the hydroconversion of n-octane. On iridium/silica, decalin hydroconversion starts at ca. 250-300 °C, and no skeletal isomerization occurs. The first step is rather hydrogenolytic opening of one six-membered ring to form the direct ring-opening products butylcyclohexane, 1-methyl-2-propylcyclohexane and 1,2- diethylcyclohexane. These show a consecutive hydrogenolysis, either of an endocyclic carboncarbon bond into open-chain decanes or of an exocyclic carboncarbon bond resulting primarily in methane and C9 naphthenes. The latter can undergo a further endocyclic hydrogenolysis leading to open-chain nonanes. All individual C10 and C9 hydrocarbons predicted by this direct ring-opening mechanism were identified in the products generated on the iridium/silica catalysts. The carbon-number distributions of the hydrocracked products C9- show a peculiar shape resembling a hammock and could be readily predicted by simulation of the direct ring-opening mechanism. Platinum on silica was found to require temperatures around 350-400 °C at which relatively large amounts of tetralin and naphthalene are formed. The most abundant primary products on Pt/silica are spiro[4.5]decane and butylcyclohexane which can be readily accounted for by the well known platinum-induced mechanisms described in the literature for smaller model hydrocarbons, namely the bond-shift isomerization mechanism and hydrogenolysis of a secondary-tertiary carboncarbon bond in decalin.
- Haas, Andreas,Rabl, Sandra,Ferrari, Marco,Calemma, Vincenzo,Weitkamp, Jens
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experimental part
p. 97 - 109
(2012/07/13)
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- Hydroisomerization of n-octane on molybdenum based catalyst
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Balanced metal-acid bifunctional MoO2-x(OH)y catalytic system has been prepared. 2-3 monolayers of this phase on the sample surface were obtained following controlled reduction by hydrogen of equivalent 5 monolayers of MoO3/sub
- Al-Kandari,Al-Kharafi,Katrib
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scheme or table
p. 141 - 148
(2010/11/03)
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- Preparation of highly active and dispersed platinum nanoparticles on mesoporous Al-MCM-48 and their activity in the hydroisomerisation of n-octane
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Platinum nanoparticles supported on Al-MCM-48 materials have been prepared. The resultant catalysts have been characterized by means of XRD, N2 physisorption experiments, scanning electron microscopy (SEM), transmission electron microscopy (TEM
- Campelo, Juan M.,Lee, Adam F.,Luque, Rafael,Luna, Diego,Marinas, Jose M.,Romero, Antonio A.
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scheme or table
p. 5988 - 5995
(2009/06/05)
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- Disproportionation of hydrocarbons
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A novel hydrocarbon disproportionation process is provided and includes contacting a hydrocarbon feed comprising at least one paraffin with a disproportionation catalyst comprising a support component, a metal, and a halogen in a disproportionation reaction zone under disproportionation reaction conditions.
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- Catalyst and process for contacting a hydrocarbon and ethylene
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A process of contacting at least one feed hydrocarbon, containing three to about seven carbon atoms per molecule, and ethylene in a hydrocarbon-containing fluid in the presence of a catalyst composition to provide at least one product hydrocarbon isomer containing about four to about nine carbon atoms per molecule is provided. The at least one feed hydrocarbon can be selected from paraffins, isoparaffins, and the like and combinations thereof. The catalyst composition contains a hydrogen halide component, a sulfone component, and a metal halide component.
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- Alkene oligomerization process
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A process for oligomerising alkenes having from 3 to 6 carbon atoms which comprises contacting a feedstock comprising a) one or several alkenes having x carbon atoms, and, b) optionally, one or several alkenes having y carbon atoms, x and y being different, with a catalyst containing a zeolite of the MFS structure type, under conditions to obtain selectively oligomeric product containing predominant amounts of certain oligomers. The process is carried out at a temperature comprised between 125 and 175° C. when the feedstock contains only alkenes with 3 carbon atoms and between 140 and 240° C., preferably between 140 and 200° C. when the feedstock contains comprises at least one alkene with 4 or more carbon atoms.
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- Pt/SAPO-5 and Pt/SAPO-11 as Catalysts for the Hydroisomerization and Hydrocracking of n-Octane
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n-Octane hydroisomerization and hydrocracking on SAPO-5 and SAPO-11 catalysts containing 0.5 wt.percent Pt have been investigated in a flow reactor over a wide range of temperatures (573-708 K) and pressures (atmospheric, 3 and 5 bar).These studies have shown that hydroisomerization is a function of the total conversion.The primary products obtained with n-octane were the monobranched isomers.Multibranched feed isomers and cracked products were formed in subsequent reactions.In all cases, hydrogen pressure had a strong influence on the activity and time-on-stream deactivation.Hydroisomerization can be considered to be the primary reaction, with hydrocracking occurring to a significant extent only at higher conversions (>40percent for Pt/SAPO-5 and >65percent for Pt/SAPO-11).The selectivity patterns found in these molecular-sieve catalysts are interpreted in terms of a series of reaction pathways incorporating both confinement effects and shape selectivity factors.
- Campelo, J. M.,Lafont, F.,Marinas, J. M.
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p. 1551 - 1556
(2007/10/02)
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- ALKANE DEHYDROCYCLIZATION AND ALKYLCYCLOPENTANE CONVERSIONS AT 13.8 bar (200 psi) WITH Pt-Al2O3 CATALYSTS
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The selectivity, defined as aromatics/isoalkanes, for the formation of aromatics is greater for the conversion of n-alkanes than for the conversion of alkylcyclopentanes with a platinum nonacidic alumina catalyst.Alkylcyclopentanes undergo hydrogenolysis to isoalkanes with the same carbon number at least ten to twenty times faster than they react to form aromatics over this catalyst.The results do not support an aromatization mechanism that includes the formation of five carbon ring intermediates.
- Hardy, Rita H.,Davis, Burtron H.
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p. 269 - 278
(2007/10/02)
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